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Record W3086852369 · doi:10.1029/2020gb006821

Glacial Dust Surpasses Both Volcanic Ash and Desert Dust in Its Iron Fertilization Potential

2021· article· en· W3086852369 on OpenAlexaboutno aff
B. G. Koffman, Meg Yoder, Taylor Methven, Lena Hanschka, Helen B. Sears, P. L. Saylor, Kristi L. Wallace

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2021
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsnot available
FundersDean of the Faculty of Arts and Sciences, Dartmouth CollegeColby College
KeywordsIron fertilizationVolcanic ashGeologySubarctic climateGlacial periodSedimentGlacierGeochemistryVolcanoEnvironmental chemistryMineralogyOceanographyGeomorphologyChemistryNutrientPhytoplankton

Abstract

fetched live from OpenAlex

Abstract The subarctic Pacific Ocean and Bering Sea comprise the second‐largest high nitrate, low chlorophyll region in the world, where primary production is limited by the availability of iron (Fe). To estimate the potential impact of different terrestrial aerosol Fe sources on marine ecosystems, we performed a suite of laboratory assessments following established protocols, including: (1) leaching with Milli‐Q water, (2) sequential extractions, (3) complete acid digestions, (4) X‐ray diffraction, and (5) grain size analysis. Measurements were performed on 20 fine‐grained (<5 μm) glacier‐derived sediments from Alaska and the Yukon, two fresh, never‐wetted volcanic ashes (Redoubt 2009 and Pavlof 2016), and six weathered ashes (Redoubt and Augustine) which span the past ∼8,700 years. We compared results to published data on Asian desert‐derived sediments, finding that the glacier‐derived sediments have five times higher easily reducible Fe (median 2.3 ± 0.6 wt.%) than desert‐derived samples (0.49 ± 0.1 wt.%) and fourteen times higher easily reducible Fe than fresh ash (0.16 ± 0.1 wt.%). In addition, fractional Fe solubility was higher in glacial sediment (median cumulative 0.31 ± 0.11% Fe S ) than volcanic ash (0.04 ± 0.02% Fe S ). Glacial sediments contained higher concentrations of other bioactive metals including Co, Ni, Cu, Zn, Mo, Cd, and Pb. Results suggest that glacier‐derived dust may provide the subarctic Pacific with more bioavailable iron per unit mass than either volcanic ash or Asian desert‐derived dust.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.044
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.212
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations30
Published2021
Admission routes1
Has abstractyes

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