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Record W3088110657 · doi:10.1039/d0em00311e

Emerging investigator series: heterogeneous OH oxidation of primary brown carbon aerosol: effects of relative humidity and volatility

2020· article· en· W3088110657 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnvironmental Science Processes & Impacts · 2020
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsUniversity of TorontoToronto Public Health
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsRelative humidityAerosolVolatility (finance)Primary (astronomy)Series (stratigraphy)Environmental scienceMeteorologyAtmospheric sciencesChemistryEconometricsMathematicsPhysicsGeology

Abstract

fetched live from OpenAlex

(associated with carboxylic acids), the O : C ratio, and the carbon oxidation state, consistent with extensive functionalization. These composition changes corresponded first to very rapid absorption enhancement and then bleaching. Net bleaching was observed after the equivalent of 10 h residence time in the atmosphere. The evolution did not depend strongly on RH, consistent with homogeneously well-mixed primary BrC even at 15% RH at room temperature. In contrast, the evolution did depend strongly on the pre-treatment of the particles, such that only bleaching occurred for particles treated at 200 °C. This suggests that lower volatility constituents of ambient primary BrC have less capacity for absorption enhancement in the atmosphere upon heterogeneous oxidation, potentially as they are already more functionalized and/or oligomeric.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.138
Threshold uncertainty score0.555

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.190
Teacher spread0.181 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it