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Record W3092634610 · doi:10.1002/lno.11568

Predicting atrazine concentrations in waterbodies across the contiguous United States: The importance of land use, hydrology, and water physicochemistry

2020· article· en· W3092634610 on OpenAlexafffund
Marieke Beaulieu, Hubert Cabana, Zofia E. Taranu, Yannick Huot

Bibliographic record

VenueLimnology and Oceanography · 2020
Typearticle
Languageen
FieldEnvironmental Science
TopicSoil and Water Nutrient Dynamics
Canadian institutionsEnvironment and Climate Change CanadaUniversité de Sherbrooke
FundersFonds de recherche du Québec – Nature et technologiesNatural Sciences and Engineering Research Council of Canada
KeywordsAtrazineEnvironmental scienceHydrology (agriculture)Water qualityWatershedSurface waterEutrophicationContaminationAgriculturePesticideEcologyEnvironmental engineeringBiologyNutrientGeology

Abstract

fetched live from OpenAlex

Abstract Atrazine contamination is ubiquitous in North American surface waters, but the dependency of the herbicide's distribution on landscape and within‐lake processes is currently poorly known. We sought to identify novel predictors of atrazine and to build a coherent framework to model its concentration in waterbodies through the development of binomial‐gamma hurdle models and LASSO regression models. We constructed models for over 900 waterbodies in the contiguous United States using data from the 2012 U.S. EPA National Lake Assessment, the 2012 U.S. Department of Agriculture CropScape and the Global HydroLAB HydroLAKES databases. Atrazine was detected in 32% of U.S. waterbodies, with a mean concentration of 0.17 μ g L −1 when detected. The two‐part hurdle model explained as much as 75% of the variance in atrazine across a spatially and temporally heterogeneous landscape. Three predictors explained 31% of the variability in atrazine detection in U.S. waterbodies, where the proportion of corn + soy cultures in the watershed was the most important variable. Once atrazine was detected, our models explained an additional 29% of the variability in atrazine concentrations, where the estimated areal weight of atrazine application (kg atrazine km 2 ) in the watershed was the most important predictor. Spatially, water quality variables associated with eutrophication were linked to increased levels of atrazine contamination while cooler water temperatures and natural lakes and landscapes were associated with decreased levels of contamination. Our results suggest that changes in land‐use practices may be the most effective way to mitigate atrazine contamination in waterbodies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.450

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.207
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations40
Published2020
Admission routes2
Has abstractyes

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