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Record W3092943692 · doi:10.22215/etd/2014-10137

Fluid Dynamics Modelling and Experimental Studies of the Flowing Electrolyte Channel in a Flowing Electrolyte - Direct Methanol Fuel Cell

2014· dissertation· en· W3092943692 on OpenAlexafffund
Eric Duivesteyn

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsCarleton University
FundersNatural Sciences and Engineering Research Council of CanadaOntario Centres of Excellence
KeywordsElectrolyteDirect methanol fuel cellPorosityPressure dropMethanolCathodeVolumetric flow ratePermeability (electromagnetism)Materials scienceMethanol fuelChemical engineeringDrop (telecommunication)ChemistryAnalytical Chemistry (journal)MembraneChromatographyMechanicsComposite materialAnodeElectrical engineeringElectrodeEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Fuel cells, and direct methanol fuel cells in particular, are a technology with intriguing potential.However, methanol crossover is a significant concern in direct methanol fuel cells that reduces power and efficiency.The flowing electrolyte -direct methanol fuel cell is a concept intended to combat this issue by using a sulphuric acid flowing electrolyte layer to remove crossed-over methanol before it can reach the cathode.Hydrodynamic modelling of the flowing electrolyte channel was conducted in order to investigate the flow characteristics in this porous channel and analyze its response to various parameters.It was concluded that pressure drop decreases with temperature, is proportional to volume flux but unaffected by channel thickness, and can be reduced by increasing permeability, which can be achieved with higher porosities and pore diameters.Experimental studies noted improved cell performance at higher temperatures, but limited improvements at higher volume fluxes, likely due to leakage associated with higher pressure drops.Experimentally estimated permeability values had some discrepancy with theoretical values, highlighting the sensitivity of permeability values to imprecise parameters.It was recommended that the flowing electrolyte channel should be very thin with a higher sphere diameter and lower porosity with a flow rate high enough to effectively negate methanol crossover.However, a possible alternative may be to use a higher porosity, but increase the flow rate to achieve the same performance; this may result in a lower pressure drop.4.4.1 General Behaviour .........

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.029

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.000
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.221
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2014
Admission routes2
Has abstractyes

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