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Record W3096803806 · doi:10.1002/cjce.23922

Esterification of <scp><i>2</i>‐keto‐L</scp>‐gulonic acid and ethanol by pervapouration using <scp>NaA</scp> zeolite membrane

2020· article· en· W3096803806 on OpenAlexvenueno aff
Lei Zhang, Hao Zhang, Huijian Shang

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicMembrane Separation and Gas Transport
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryEthanolMembraneChromatographyMass transferOrganic chemistryBiochemistry

Abstract

fetched live from OpenAlex

Abstract Esterification of 2‐Keto‐gulonic acid is an important process in the production of vitamin C. The traditional esterification reaction process improves the esterification rate with large energy consumption. In this study, the mass transfer model of the pervapouration process was established based on the separation effect of the zeolite membrane. The mass transfer rule was studied, and the reaction‐membrane separation coupling technology was applied to the esterification process of 2‐Keto‐L‐gulonic acid and ethanol. The esterification rate of 2‐Keto‐L‐gulonic acid was increased to 95.37%. At this time, the reaction conditions were as follows: (a) the temperature was 55°C, (b) the alkyd molar ratio was 40.31:1, and (c) and the feed rate was 20.77 mL · min −1 .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.058
Threshold uncertainty score0.771

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.196
Teacher spread0.181 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2020
Admission routes1
Has abstractyes

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