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Record W3099952038

Optical Property Trends in Metal/Polymer (Ag/PVDF) Nanocomposites: A Computational Study

2011· dissertation· en· W3099952038 on OpenAlex
Christopher K. Rowan

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueUVic’s Research and Learning Repository (University of Victoria) · 2011
Typedissertation
Languageen
FieldMaterials Science
TopicPolymer Nanocomposite Synthesis and Irradiation
Canadian institutionsnot available
FundersWestern Canada Research Grid
KeywordsNanocompositeMaterials scienceMetalPolymerProperty (philosophy)Polymer nanocompositeComposite materialNanotechnologyPolymer chemistryPolymer scienceMetallurgy
DOInot available

Abstract

fetched live from OpenAlex

Metal-polymer nanocomposite materials were found to have highly tunable opti-
\ncal properties. Density functional theory-based calculations were employed to study
\ntrends in Ag/polyvinylidene fluoride nanocomposite optical properties. The frequency-
\ndependent imaginary part of the dielectric constant was calculated from dipolar inter-
\nband transitions. The metallic inclusion introduced both occupied and unoccupied
\nstates into the large polymer band gap. Thus, higher inclusion volume fractions
\ngenerally led to stronger composite optical response. Spectra from monodisperse sys-
\ntems correlated well with nanoparticle quantum confinement models. A polydisperse
\nsystem exhibited optical properties that correlated best with interparticle distances
\nalong the field direction. Nanodisk and nanorod-shaped inclusions had tunable re-
\nsponse from field polarization, aspect ratio, crystallographic projections, and nanorod
\nend-cap morphology.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.741
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.282
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it