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Record W3107151777 · doi:10.1002/aelm.202000804

Short Alkyl Chain Engineering Modulation on Naphthalene Flanked Diketopyrrolopyrrole toward High‐Performance Single Crystal Transistors and Organic Thin Film Displays

2020· article· en· W3107151777 on OpenAlexafffund
Qian Liu, Sudam Chavhan, Hantang Zhang, Huabin Sun, Aidan J. Brock, Sergei Manzhos, Yingqian Chen, Krishna Feron, Steven E. Bottle, John C. McMurtrie, Jwo‐Huei Jou, H.C Chen, Mangey Ram Nagar, Wenping Hu, Yong‐Young Noh, Yonggang Zhen, Prashant Sonar

Bibliographic record

VenueAdvanced Electronic Materials · 2020
Typearticle
Languageen
FieldEngineering
TopicOrganic Electronics and Photovoltaics
Canadian institutionsInstitut National de la Recherche Scientifique
FundersInstitute for Future Environments, Queensland University of TechnologyAustralian Research CouncilEuropean CommissionCompute Canada
KeywordsMaterials scienceOLEDThin-film transistorDopantOptoelectronicsOrganic electronicsActive matrixAlkylTransistorElectron mobilityOrganic semiconductorFlexible electronicsActive layerDiodeNanotechnologyLayer (electronics)DopingOrganic chemistryChemistryElectrical engineering

Abstract

fetched live from OpenAlex

Abstract Studying multi‐purpose applications of a specific material is a challenging topic in the organic electronics community. In this work, through molecular engineering and smart device structure design strategy, high performance in transistors and thin film display devices is simultaneously achieved by applying a simple new dye molecule, naphthalene flanked diketopyrrolopyrrole (DPPN), as the active layer material. Short alkyl chains (hexyl or octyl side groups for H‐DPPN and O‐DPPN, respectively) are adapted to improve the hole mobility in organic thin film transistors (OTFTs) and single crystal transistors (SCTs). Specifically, H‐DPPN shows a similar hole mobility in either OTFTs or SCTs, while O‐DPPN exhibits a dramatically enhanced mobility, reaching 0.125 cm2 V−1 s−1 in SCTs. Additionally, a smart organic light emitting diode (OLED) device is designed by using DPPN molecule as the dopant with a host matrix. The promising external quantum efficiencies of 4.0% and 2.3% are achieved for H‐DPPN and O‐DPPN fabricated OLEDs. Overall, in this work, it is reported that DPP‐based small molecules can simultaneously function well in both transistors and thin film displays with high device performance through molecular and smart device engineering.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.173
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations28
Published2020
Admission routes2
Has abstractyes

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