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Record W3108440821 · doi:10.1002/cjce.23958

Ultrasound and air‐disturbance‐based enhancement of spiral microchannel extraction of <scp>Cu<sup>2+</sup></scp>

2020· article· en· W3108440821 on OpenAlexvenueno aff
Xingdong Yang, Xiao Wenqiang, Shuang Dai, Jiyan Qu, Jianhong Luo

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryExtraction (chemistry)ChromatographyMicrochannelSolventVolumetric flow rateAnalytical Chemistry (journal)Aqueous solutionAdsorptionLiquid–liquid extractionNanotechnologyMaterials science

Abstract

fetched live from OpenAlex

Abstract In this work, we evaluated the enhancement effect on the extraction of Cu2+ from water by introducing ultrasound and air disturbance in a spiral microchannel device. We used 2‐ethylhexyl phosphonic acid mono‐2‐ethylhexyl ester (P507) as an extractant and used kerosene as a solvent. The effects of flow rate, temperature, initial pH of water, organic/aqueous phase ratio (O/A), the concentration of extractant, and the inner diameter of the pipe on the extraction of Cu2+ were investigated in liquid‐liquid micro‐extraction (LLME), ultrasonic micro‐extraction (UME), and liquid‐liquid‐gas micro‐extraction (LLGME). We found that, at a similar extraction rate, the extraction capacity per unit of time of UME was five times that of LLME, and the extraction capacity per unit of time of LLGME was 10 times that of LLME. By comparing the effects of three methods on extracting Cu2+, we followed the following priority order: LLGME > UME > LLME. The results of three‐stage extraction under optimum conditions were also studied. The results revealed that the highest extraction rate of the three methods could reach about 92% with the processing time of 72 seconds under optimal conditions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.205
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2020
Admission routes1
Has abstractyes

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