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Record W3112144088 · doi:10.1016/j.pacs.2020.100228

Highly sensitive broadband differential infrared photoacoustic spectroscopy with wavelet denoising algorithm for trace gas detection

2020· article· en· W3112144088 on OpenAlexafffund
Lixian Liu, Huiting Huan, Wei Li, Andreas Mandelis, Yafei Wang, Le Zhang, Xueshi Zhang, Xukun Yin, Yuxiang Wu, Xiaopeng Shao

Bibliographic record

VenuePhotoacoustics · 2020
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsUniversity of Toronto
FundersFundamental Research Funds for the Central UniversitiesChina Postdoctoral Science FoundationNatural Sciences and Engineering Research Council of CanadaNatural Science Foundation of Shaanxi ProvinceNational Natural Science Foundation of China
KeywordsTrace gasNoise reductionPhotoacoustic spectroscopyNoise (video)Materials scienceWaveletOpticsFourier transform infrared spectroscopyAnalytical Chemistry (journal)Photoacoustic imaging in biomedicinePhysicsAcousticsChemistryComputer scienceArtificial intelligence

Abstract

fetched live from OpenAlex

Enhancement of trace gas detectability using photoacoustic spectroscopy requires the effective suppression of strong background noise for practical applications. An upgraded infrared broadband trace gas detection configuration was investigated based on a Fourier transform infrared (FTIR) spectrometer equipped with specially designed T-resonators and simultaneous differential optical and photoacoustic measurement capabilities. By using acetylene and local air as appropriate samples, the detectivity of the differential photoacoustic mode was demonstrated to be far better than the pure optical approach both theoretically and experimentally, due to the effectiveness of light-correlated coherent noise suppression of non-intrinsic optical baseline signals. The wavelet domain denoising algorithm with the optimized parameters was introduced in detail to greatly improve the signal-to-noise ratio by denoising the incoherent ambient interference with respect to the differential photoacoustic measurement. The results showed enhancement of sensitivity to acetylene from 5 ppmv (original differential mode) to 806 ppbv, a fivefold improvement. With the suppression of background noise accomplished by the optimized wavelet domain denoising algorithm, the broadband differential photoacoustic trace gas detection was shown to be an effective approach for trace gas detection.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.232
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations87
Published2020
Admission routes2
Has abstractyes

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