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Record W3113701308 · doi:10.1002/cjce.24006

Pulse‐assisted fluidization of nanoparticles: Case of lithium iron phosphate material

2020· article· en· W3113701308 on OpenAlexafffundvenue
Samira Aghaee Sarbarze, Mohammad Latifi, Majid Rasouli⃰, Steeve Rousselot, Mickaël Dollé, Jamal Chaouki

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2020
Typearticle
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsUniversité de MontréalDuPont (Canada)Polytechnique Montréal
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsLithium iron phosphateFluidizationMaterials scienceNanoparticleLithium (medication)Chemical engineeringCoatingRaw materialCarbon fibersFluidized bedNanotechnologyElectrodeComposite materialElectrochemistryChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Pulse‐assisted fluidization was developed for the fluidization of nanoparticles at high‐temperature processes (eg, above 600°C, depending on the material of interest). The technique was employed for carbon coating of lithium iron phosphate (LFP) nanoparticles with a gas‐phase carbon precursor (ie, propylene) through chemical vapour deposition (PAFB‐CVD). LFP has been extensively investigated as an environmentally friendly and cost‐effective cathode material of rechargeable lithium‐ion batteries. LFP nanoparticles of this research were, in fact, cohesive secondary particles of Geldart's group C. The CVD tests were carried out at temperatures between 600°C‐750°C. Uniform layers of carbon were deposited on the surface of LFP nanoparticles with a thickness less than 10 nm while particles were not sintered under high temperature operations. Also, the generated C‐LFP material held a superior electrical conductivity of 10 10 times more than the conductivity of uncoated raw LFP; it also featured a significant enhancement of discharge capacity despite the considerable delay between the production of raw LFP nanoparticles and the CVD process.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.199
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2020
Admission routes3
Has abstractyes

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