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Record W3115373764 · doi:10.1021/acsami.0c16582

Solvent-Free Fabrication of Robust Superhydrophobic Powder Coatings

2020· article· en· W3115373764 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Applied Materials & Interfaces · 2020
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsWestern University
FundersNatural Sciences and Engineering Research Council of CanadaChina Scholarship Council
KeywordsMaterials scienceSuperhydrophobic coatingSurface energyContact angleCoatingAbrasion (mechanical)Composite materialFabricationSuperhydrophilicityPolytetrafluoroethyleneMicroscale chemistryLubricationNanoparticleSurface modificationNanotechnologyChemical engineering

Abstract

fetched live from OpenAlex

Superhydrophobicity originating from the "lotus effect" enables novel applications such as self-cleaning, anti-fouling, anti-icing, anti-corrosion, and oil-water separation. However, their real-world applications are hindered by some main shortcomings, especially the organic solvent problem, complex chemical modification of nanoparticles, and poor mechanical stability of obtained surfaces. Here, we report for the first time the solvent-free, chemical modification-free, and mechanically, chemically, and UV robust superhydrophobic powder coatings. The coatings were fabricated by adding commercially available polytetrafluoroethylene (PTFE) particles into powder coatings and by following the regular powder-coating processing route. The formation of such superhydrophobic surfaces was attributed to PTFE particles, which hindered the microscale leveling of powder coatings during curing. Through adjusting the dosage of PTFE, the hydrophobicity of obtained coatings can be tuned in a large range (water contact angle from 92 to 162°). The superhydrophobic coatings exhibited remarkable mechanical robustness against abrasion because of the unique hierarchical micro/nanoscale roughness and low surface energy throughout the coating and the solid lubrication effect of PTFE particles. The coatings also have robustness against chemical corrosion and UV irradiation owing to high bonding energy and chemical inertness of PTFE. Moreover, the coatings show attractive performances including self-cleaning, anti-rain, anti-snow, and anti-icing. With these multifaceted features, such superhydrophobic coatings are promising for outdoor applications. This study also contributes to the preparation of robust superhydrophobic surfaces in an environmentally friendly way.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.033
GPT teacher head0.233
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it