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Record W3119478021 · doi:10.1126/sciadv.abd4248

Single-crystalline epitaxial TiO film: A metal and superconductor, similar to Ti metal

2021· article· en· W3119478021 on OpenAlexafffund
Fengmiao Li, Yuting Zou, Myung‐Geun Han, Kateryna Foyevtsova, Hyungki Shin, Sangjae Lee, Chong Liu, Kidae Shin, Stephen D. Albright, Ronny Sutarto, Feizhou He, B. A. Davidson, F. J. Walker, Charles Ahn, Yimei Zhu, Zhi Gang Cheng, Ilya Elfimov, G. A. Sawatzky, Ke Zou

Bibliographic record

VenueScience Advances · 2021
Typearticle
Languageen
FieldMaterials Science
TopicElectronic and Structural Properties of Oxides
Canadian institutionsCanadian Light Source (Canada)University of British Columbia
FundersGovernment of SaskatchewanNatural Sciences and Engineering Research Council of CanadaBasic Energy SciencesNational Key Research and Development Program of China Stem Cell and Translational ResearchCanadian Institutes of Health ResearchNational Research Council CanadaCanada Foundation for InnovationNational Natural Science Foundation of ChinaOffice of ScienceCanada First Research Excellence FundUniversity of SaskatchewanU.S. Department of Energy
KeywordsEpitaxyMetalSuperconductivityMaterials scienceTransition metalNanotechnologyMetallurgyCondensed matter physicsChemistryCatalysisPhysics

Abstract

fetched live from OpenAlex

We adapt a closely lattice-matched MgO(001) substrate and report the successful growth of single-crystalline TiO(001) film using molecular beam epitaxy. This enables a first-time study of stoichiometric TiO thin films, showing that TiO is metal but in proximity to Mott insulating state. We observe a transition to the superconducting phase below 0.5 K close to that of Ti metal. Density functional theory (DFT) and a DFT-based tight-binding model demonstrate the extreme importance of direct Ti-Ti bonding in TiO, suggesting that similar superconductivity exists in TiO and Ti metal. Our work introduces the new concept that TiO behaves more similar to its metal counterpart, distinguishing it from other 3d transition-metal monoxides.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.261
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations34
Published2021
Admission routes2
Has abstractyes

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Same venueScience AdvancesSame topicElectronic and Structural Properties of OxidesFrench-language works237,207