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Record W3126048931 · doi:10.1021/jacs.0c11265

<i>In Situ</i> Localized Polysulfide Injector for the Activation of Bulk Lithium Sulfide

2021· article· en· W3126048931 on OpenAlexafffund
Matthew Li, Jun Lü, Jiayan Shi, Seoung‐Bum Son, Dan Luo, Ira Bloom, Zhongwei Chen, Khalil Amine

Bibliographic record

VenueJournal of the American Chemical Society · 2021
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsUniversity of Waterloo
FundersWaterloo Institute for Nanotechnology, University of WaterlooNatural Sciences and Engineering Research Council of CanadaUniversity of WaterlooU.S. Department of Energy
KeywordsPolysulfideChemistryElectrolyteCathodeInjectorSulfideSulfurLithium (medication)Battery (electricity)RedoxCommercializationIn situInorganic chemistryChemical engineeringOrganic chemistryElectrodePhysical chemistry

Abstract

fetched live from OpenAlex

The activation of commercial Li2S remains to be one of the key challenges against its commercialization as a starting cathode material for a sulfur-based Li-ion battery system. In this work we take advantage of the lower oxidation potential of commercial Na2S (1–3 wt%) to serve as an in situ and local polysulfide injector for the activation of commercial Li2S (70 wt%). In contrast to applying pre-solvated redox mediators, this technique allows for the activation of commercial Li2S at lower voltages with an electrolyte content as low as 3 μL mg–1Li2S at 3 mgmgLi2S cm–2 and 4 μL mg–1Li2S at 6.5 mgLi2S cm–2 without any other material modification.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.204

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.237
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations45
Published2021
Admission routes2
Has abstractyes

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