Synthesis of a novel Ce(<scp>iii</scp>)/melamine coordination polymer and its application for corrosion protection of AA2024 in NaCl solution
Bibliographic record
Abstract
groups, instead of the N atoms of the triazine ring, for which we propose a mechanism of interaction. In addition, Biovia Materials Studio package was applied to determine and investigate the molecular structure of the CMCP. All simulations were done using COMPASS force-field theory and atom-based method for summation of electrostatic and van de Waals forces. The application of the CMCP for the corrosion inhibition of AA2024 in 3.5% NaCl solution was tested using the potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results point out that the presence of cerium as cerium(iii) in the CMCP structure plays the fundamental role of inhibition, whereby the inhibition mechanism occurs by cathodic oxidation of Ce(iii) to Ce(iv) and cyclic reduction of Ce(iv) to Ce(iii) by melamine part of CMCP.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".