MétaCan
Menu
Back to cohort
Record W3126931604 · doi:10.1002/047084289x.rn02341

2,6‐Difluorophenyl Sulfamate

2021· other· en· W3126931604 on OpenAlexaff
Nour Tanbouza, Thierry Ollevier

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2021
Typeother
Languageen
FieldChemistry
TopicSynthesis and Catalytic Reactions
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsFormic acidAminationChemistryDimethylacetamideSolubilityAcetoneChlorideOrganic chemistryNuclear chemistryMedicinal chemistryPolymer chemistrySolventCatalysis

Abstract

fetched live from OpenAlex

[1186393-80-5] C6H5F2NO3S (MW 209.17) InChI = 1S/C6H5F2NO3S/c7-4-2-1-3-5(8)6(4)12-13(9,10)11/h1-3H,(H2,9,10,11) InChIKey = AYTBQOODKYBHGK-UHFFFAOYSA-N (CH amination,1–7 aziridination,6,8,9 SN1 amination,10 sulfamoylation11) Physical Data: mp 99–101 °C.12 Solubility: soluble in most organic solvents. Form Supplied in: commercially available as a white solid. Preparative Method: prepared by reaction of 2,6-difluorophenol with sulfamoyl chloride in N,N-dimethylacetamide (sulfamoyl chloride is prepared from chlorosulfonyl isocyanate and formic acid).12 Purification: recrystallized from hot acetone layered with CHCl3.1

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.207
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.2070.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.239
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicSynthesis and Catalytic ReactionsFrench-language works237,207