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Record W3127693375 · doi:10.1002/cptc.202000265

Graphitic Carbon Nitride (g‐C<sub>3</sub>N<sub>4</sub>) Nanosheets as a Multipurpose Material for Detection of Amines and Solar‐Driven Hydrogen Production

2021· article· en· W3127693375 on OpenAlexaff
Manh Hiep Vu, Chinh Chien Nguyen, Trong‐On Do

Bibliographic record

VenueChemPhotoChem · 2021
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsGraphitic carbon nitridePhotocatalysisAqueous solutionCalcinationAmine gas treatingCarbon nitrideHydrogen productionMaterials scienceCarbon fibersChemical engineeringHydrogenPhotochemistryInorganic chemistryCatalysisChemistryOrganic chemistryComposite number

Abstract

fetched live from OpenAlex

Abstract Graphitic carbon nitride nanosheets decorated by multiple functional groups (denoted as CN−KNa) were as a multipurpose material, both in photocatalytic applications and as a photo‐induced indicator. The presented g‐C 3 N 4 is fabricated via a facile alkali‐salt‐assisted calcination method. The structural analysis reveals significant changes in the structure of the host CN−KNa nanosheets associated with the existence of multiple functional groups (for example, hydroxy, carbonyl, and cyano groups). Such modifications lead to enhanced light absorption and charge separation, resulting in an efficient photocatalyst not only for solar‐driven hydrogen production but also for primary amine detection in aqueous solution. Thus, the solar light driven photocatalytic hydrogen evolution yield using the synthesized CN−KNa sample is found to be 50.3 μmol h −1 , which is approximately 14 times higher than that of bulk g‐C 3 N 4 . More importantly, this functional‐group‐decorated CN−KNa facilitated electron transportation between CN−KNa and amine compounds, causing a colour change in the solution mixture, which has been observed for the first time. This novel observation indicates that CN−KNa can be considered a new class of photo‐induced indicator agent to detect primary amine compounds in aqueous solution.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.228
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations21
Published2021
Admission routes1
Has abstractyes

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