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Record W3129101067 · doi:10.1002/ep.13608

Adsorption of reduced chromium(<scp>VI</scp>) ions by vitamin C tablets onto a tellurato‐functionalized cellulose derivative and its composite with <i>Cyanobacteria</i> green algae in aqueous media

2021· article· en· W3129101067 on OpenAlexafffund
Eman M. Saad, Ian S. Butler

Bibliographic record

VenueEnvironmental Progress & Sustainable Energy · 2021
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsMcGill University
FundersMcGill University
KeywordsAdsorptionChemistryNuclear chemistryMetal ions in aqueous solutionChromiumInorganic chemistryAscorbic acidIonOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract The removal of toxic chromium(VI) ions from wastewaters in the environment are of considerable importance throughout the world as these ions are known to cause severe medical problems in living organisms. This article describes a novel reduction process for Cr(VI) ions to the less toxic Cr(III) ions in typical wastewaters by using ecofriendly vitamin C tablets as a source of ascorbic acid, which completely reduces Cr(VI) to Cr(III) ions. The efficient adsorption of reduced Cr(VI) ions onto cellulose functionalized with sodium‐tellurate, Cell‐TeO(OH) 4 (ONa)/Cell‐Cl {Cell‐Te} , both in the absence and the presence of Cyanobacteria green algae (CBGA), has been accomplished. This green algae has polysaccharide binding groups that enhance the adsorption of heavy metal ions. The uptake of reduced Cr(VI) ions by the two sorbents are dependent on the initial pH, contact time, temperature, presence of foreign ions, sorbent dose, and initial Cr(VI) ion concentration. The maximum uptakes of reduced Cr(VI) ions by {Cell‐Te} and Cell‐TeO(OH) 4 (ONa)/Cell‐Cl:CBGA; 3:2 w/w {Cell‐Te‐CBGA} are 56.5 and 88.7 mg g −1 , respectively. The hydroxyl and amide groups on the surface of the CBGA most probably play a significant role in facilitating the adsorption capacities of the two sorbents toward Cr(VI) ions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.098
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.180
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2021
Admission routes2
Has abstractyes

Explore more

Same venueEnvironmental Progress & Sustainable EnergySame topicAdsorption and biosorption for pollutant removalFrench-language works237,207