Technical note: Evaporating water is different from bulk soil water in δ <sup>2</sup> H and δ <sup>18</sup> O
Bibliographic record
Abstract
Abstract. Soil evaporation is a key process in the water cycle and can be conveniently quantified with δ2H and δ18O in bulk surface soil water (BW). However, recent research shows that larger soil pore water evaporates first and differs from small pore water in δ2H and δ18O, which disqualifies quantification of evaporation from BW δ2H and δ18O. We hypothesize that BW has different isotopic compositions than evaporating water (EW). Therefore, our objectives are to test the hypothesis, and to evaluate if the difference alters the calculated evaporative water loss. We measured isotopic composition in soil water in two continuous evaporation periods in a summer maize field. Period Ⅰ had a duration of 32 days following a precipitation event and Period Ⅱ lasted 24 days following an irrigation event with a 2H-enriched water. BW was obtained by cryogenically extracting water from samples of 0–5 cm soil taken every three days; EW was derived from condensation water collected every two days on plastic film placed on soil surface. Results showed that when newly added water was heavier than pre-event BW, δ2H of BW in Period Ⅱ decreased with the increase of evaporation time, indicating evaporation of heavy water; when newly added water was lighter than pre-event BW, δ2H and δ18O of BW in Period Ⅰ and δ18O of BW in Period Ⅱ increased with increasing evaporation time, suggesting evaporation of light water. Moreover, relative to BW, EW had significantly smaller δ2H and δ18O in Period Ⅰ and significantly smaller δ18O in Period Ⅱ (p 0.05). Our results have important implication for quantifying evaporation process with water stable isotopes.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.003 | 0.006 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.001 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.001 | 0.002 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.002 | 0.001 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.016 | 0.006 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".