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Record W3134832133 · doi:10.1002/smll.202007025

CO<sub>2</sub> Footprint of Thermal Versus Photothermal CO<sub>2</sub> Catalysis

2021· review· en· W3134832133 on OpenAlex
Shenghua Wang, Athanasios A. Tountas, Wangbo Pan, Jianjiang Zhao, Le He, Wei Sun, Deren Yang, Geoffrey A. Ozin

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueSmall · 2021
Typereview
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsUniversity of Toronto
FundersNational Key Research and Development Program of ChinaNatural Sciences and Engineering Research Council of CanadaSoochow UniversityTaiyuan University of TechnologyZhejiang UniversityNational Natural Science Foundation of ChinaState Key Laboratory of Silicon MaterialsGovernment of Canada
KeywordsPhotothermal therapyProcess engineeringCatalysisFossil fuelMaterials scienceNanotechnologyEnvironmental scienceElectricityChemical engineeringChemistryOrganic chemistryPhysicsEngineering

Abstract

fetched live from OpenAlex

Abstract Transformation of CO 2 into value‐added products via photothermal catalysis has become an increasingly popular route to help ameliorate the energy and environmental crisis derived from the continuing use of fossil fuels, as it can integrate light into well‐established thermocatalysis processes. The question however remains whether negative CO 2 emission could be achieved through photothermal catalytic reactions performed in facilities driven by electricity mainly derived from fossil energy. Herein, we propose universal equations that describe net CO 2 emissions generated from operating thermocatalysis and photothermal reverse water–gas shift (RWGS) and Sabatier processes for batch and flow reactors. With these reactions as archetype model systems, the factors that will determine the final amount of effluent CO 2 can be determined. The results of this study could provide useful guidelines for the future development of photothermal catalytic systems for CO 2 reduction.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Other design · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.891
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0050.003
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.313
Teacher spread0.270 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it