Flexible Conductive Substrate Incorporating a Submicrometer Co-continuous Polyaniline Phase within Polyethylene by Controlled Crazing
Bibliographic record
Abstract
A polyethylene film with an incorporated nanodispersed polyaniline conductive network was developed by controlled crazing in a high-pressure reactor while immersed in an emulsified medium of aniline in chloroform. The resulting conductive material exhibited an average through-plane electron conductivity of 2 × 10–2 S·cm–1, within an order of magnitude of brittle doped polyaniline (1.2 × 10–1 S·cm–1), yet retained the ductility of the polyethylene matrix. It was also shown that 90% of the original conductivity was retained after 1% elongation. Embedded polyaniline fibers acted both as a nucleating agent to reduce the size of crystallites for controlled crazing and as submicrometer conductive nodes, connecting neighboring conductive conduits formed inside the crazing voids, with both effects contributing to the increasing electrical permeability of the secondary phase. For comparison, montmorillonite and TiO2 particles were tested as alternative nucleating agents to verify the effect of the preliminary embedded polyaniline fibers on the matrix morphology and, consequently, the conductivity acquired.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".