Synthesis and Crystal Structure of the Chromium(III) Complex with 2-hydro-1-naphthaldehyde Semicarbazone
Bibliographic record
Abstract
The mononuclear chromium(Ⅲ) complex with 2-hydroxy-1-naphthaldehyde semicarbazone was synthesized and characterized by IR,UV-Vis,fluorescence spectra and single-crystal structure determination.The crystal structure belongs to monoclinic system,space group C2/c with a=3.535 7(8) nm,b=1.608 5(4) nm,c=0.930 52(19) nm,β=98.271(4)°,and Z=8.The crystal structure and spectra data suggest that the ligand of 2-hydro-1-naphthal-dehyde semicarbazone behaves as a tridentate chelating agent,coordinating through phenolic oxygen,nitrogen atom of C=N group and ketonic oxygen.The chromium(Ⅲ) center is a six-coordinated distorted octahedral geometry.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".