Glycothermal synthesis and photoluminescence of Mg–Si modified Ce:YAG nanophosphors
Bibliographic record
Abstract
The absorption spectrum of Ce in a YAG based host grown using the glycothermal method was modified using the addition of Mg-Si pairs. Photoluminescence intensity was dramatically improved by increasing the reaction temperature to 315 °C instead of the conventionally used 300 °C. It was found that Mg acetate and tetraethylorthosilicate (TEOS) are suitable as precursors for the glycothermal process, as EDS elemental mapping showed their homogeneous inclusion in the final product. Their addition only slightly modified the emission spectrum of Ce:YAG. It was found that increasing the reaction temperature to 315 °C yielded nanoparticles 56 ± 16 nm in size with a 3.3× enhancement in absorption and 3.7× enhancement in emission intensities compared to samples synthesized at 300 °C, and an increase in photoluminescence quantum yield from 32% to 48%. Reaction kinetics of the precursors and a proposed route for post-synthesis surface functionalization are discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".