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Record W3152860864 · doi:10.1126/sciadv.abc7318

Correcting a major error in assessing organic carbon pollution in natural waters

2021· article· en· W3152860864 on OpenAlexaff
Nianzhi Jiao, Jihua Liu, Bethanie R. Edwards, Zongqing Lv, Ruanhong Cai, Yongqin Liu, Xilin Xiao, Jianning Wang, Rui Wang, Xingyu Huang, Bixi Guo, Jia Sun, Rui Zhang, Yao Zhang, Kai Tang, Qiang Zheng, Farooq Azam, John Batt, Wei‐Jun Cai, Chen He, Gerhard J. Herndl, Paul S. Hill, David A. Hutchins, Julie LaRoche, Marlon R. Lewis, Hugh L. MacIntyre, Luca Polimene, Carol Robinson, Quan Shi, Curtis A. Suttle, Helmuth Thomas, Douglas W.R. Wallace, Louis Legendre

Bibliographic record

VenueScience Advances · 2021
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsFisheries and Oceans CanadaDalhousie University
FundersNational Key Research and Development Program of ChinaChina Ocean Mineral Resources Research and Development AssociationNatural Environment Research CouncilSight Research UKLeverhulme Trust
KeywordsEnvironmental scienceDissolved organic carbonEnvironmental chemistryPollutionChemical oxygen demandBiochemical oxygen demandAquatic ecosystemTotal organic carbonWater pollutionEnvironmental engineeringEcologyChemistryWastewaterBiology

Abstract

fetched live from OpenAlex

emissions. These problems are caused by labile DOC (LDOC) and not refractory DOC (RDOC) that resists degradation and is thus a carbon sink. For nearly a century, chemical oxygen demand (COD) has been widely used for assessment of organic pollution in aquatic systems. Here, we show through a multicountry survey and experimental studies that COD is not an appropriate proxy of microbial degradability of organic matter because it oxidizes both LDOC and RDOC, and the latter contributes up to 90% of DOC in high-latitude forested areas. Hence, COD measurements do not provide appropriate scientific information on organic pollution in natural waters and can mislead environmental policies. We propose the replacement of the COD method with an optode-based biological oxygen demand method to accurately and efficiently assess organic pollution in natural aquatic environments.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.158
Threshold uncertainty score0.916

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.237
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations89
Published2021
Admission routes1
Has abstractyes

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