Modeling the Solubility of Carbon Dioxide and 1,1,1,2-Tetrafluoroethane in Ionic Liquids Using the van der Waals and Generic Redlich–Kwong Equations of State
Bibliographic record
Abstract
In this study, we have examined the modeling of gas solubility in twenty room temperature ionic liquids based on the van der Waals and generic Redlich–Kwong equations of state and have also compared the obtained deviations with each other. The selected gases are carbon dioxide (R744) and 1,1,1,2-tetrafluoroethane (R134a). Experimental data represent a high correlation with the present equations of state. It is concluded that the absolute average deviation is less than 1% for each system, which illustrates the high accuracy and efficiency of the mentioned equations of state. Henry’s law constant and some thermodynamic properties such as enthalpy $$(\Delta {{H}^{\infty }})$$ and entropy $$(\Delta {{S}^{\infty }})$$ in infinite dilution are calculated.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".