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Record W3157127218 · doi:10.38028/esi.2021.21.1.005

NUMERICAL ESTIMATION OF CRITICAL CONDITIONS IN THERMAL EXPLOSION PROBLEM FOR A MEDIUM WITH FLUCTUATIONS OF REACTIVITY

2021· article· ru· W3157127218 on OpenAlexfundno aff
И. Г. Донской

Bibliographic record

VenueИнформационные и математические технологии в науке и управлении · 2021
Typearticle
Languageru
FieldEngineering
TopicMaterial Science and Thermodynamics
Canadian institutionsnot available
FundersSiberian Branch, Russian Academy of SciencesMinistère de l'Économie, de la Science et de l'Innovation - Québec
KeywordsInflection pointThermodynamicsReactivity (psychology)Dispersion (optics)ThermalCritical point (mathematics)Function (biology)Distribution functionDistribution (mathematics)PhysicsMechanicsMathematicsMathematical analysisQuantum mechanicsGeometry

Abstract

fetched live from OpenAlex

Формулируется задача о тепловом взрыве в среде с флуктуациями реакционной способности, которые задаются через функцию распределения энергии активации. Для дифференциального уравнения, описывающего стационарное распределение температуры в такой среде, предложена вариационная формулировка. С использованием простой пробной функции численно исследуется зависимость величины вариационного функционала от максимальной температуры. Критические условия теплового взрыва соответствуют появлению точки перегиба на этой зависимости. Расчеты показывают, что увеличение дисперсии распределения реакционной способности снижает устойчивость системы за счет уменьшения эффективной энергии активации для процесса тепловыделения. The problem of a thermal explosion in a medium with fluctuations in reactivity, which are specified through the distribution function for the activation energy, is formulated. A variational formulation is proposed for the differential equation describing the stationary temperature distribution in such a medium. Using a simple test function, the dependence of the variational functional on the value of the maximum temperature is numerically investigated. The critical conditions for a thermal explosion correspond to the appearance of an inflection point on this curve. Calculations show that an increase in the dispersion of the reactivity distribution the stability of the system decreases due to shift of the apparent activation energy of the chemical reaction.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.011
Threshold uncertainty score0.022

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.000
Science and technology studies0.0010.002
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0020.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.269
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2021
Admission routes1
Has abstractyes

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