Enhanced swelling using photothermal responsive <scp>surface‐immobilized</scp> microgels
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Unprecedented quantitative assessment of the swelling behavior of surface‐immobilized photothermal responsive microgels (PTRM) is reported. The PTRM were prepared by incorporating plasmonic gold nanoparticles (AuNPs) in thermo‐responsive cationic microgels based on poly(N‐isopropylacrylamide) (BM). The stimuli‐responsive behavior of the microgels was investigated in aqueous suspensions using Dynamic Light Scattering (DLS) and on surfaces using a Quartz Crystal Microbalance with Dissipation (QCM‐D) as well as with the Surface Forces Apparatus (SFA). Both the BM and PTRM in aqueous suspensions underwent a similar temperature‐induced volume phase transition at around 35°C. The complexation of AuNPs with the BM led to a decrease in the surface charge allowing to increase the surface grafting density. This favored a unidirectional upward swelling of the surface immobilized PTRM. The study reports significant photo‐triggered swelling responses on surface with decreases in film thickness up to 82%.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.002 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it