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Land-Use Change and Environmental Properties Alter the Quantity and Molecular Composition of Soil-Derived Dissolved Organic Matter

2021· article· en· W3165207853 on OpenAlexafffund
Huan Tong, André J. Simpson, Eldor A. Paul, Myrna J. Simpson

Bibliographic record

VenueACS Earth and Space Chemistry · 2021
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsThe Scarborough HospitalUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsDissolved organic carbonEnvironmental chemistrySoil waterSoil organic matterOrganic matterEnvironmental scienceSoil carbonTotal organic carbonAquatic ecosystemComposition (language)Carbon cycleEcosystemChemistrySoil scienceEcologyBiology

Abstract

fetched live from OpenAlex

Dissolved organic matter (DOM) is a major pool of actively cycling organic carbon in soils, and can be exported to aquatic environments. The quantity and chemistry of DOM vary with different environmental factors, such as soil properties and climate. Accordingly, the amount and composition of DOM in soil and that which is exported to aquatic systems are likely altered by land-use change, but these aspects have not been studied with various environmental factors and associated land-use gradients in detail. To address this, both native and cultivated soil samples from North and South America were used to extract soil-derived DOM. DOM samples were isolated and analyzed for total organic carbon concentration and solution-state nuclear magnetic resonance spectroscopy. The concentration of dissolved organic carbon (DOC) was significantly correlated with soil organic carbon concentration (r = 0.869, p < 0.01, n = 14) and relative soil organic matter degradation state (r = −0.578, p < 0.05, n = 14). Land-use change decreased the controls of environmental factors on the concentration of DOC but enhanced the correlations between DOM aromaticity and mean annual precipitation (r = −0.957, p < 0.01, n = 7) and sand concentration (r = −0.867, p < 0.05, n = 7). This study found that land-use conversion and environmental conditions alter the quantity and quality of DOM distinctly and uniquely. Here, we identified the main factors that regulate the formation of soil DOM and its potential mobility in soil profiles as well as export to aquatic ecosystems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.074
Threshold uncertainty score0.312

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.162
Teacher spread0.151 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2021
Admission routes2
Has abstractyes

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