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Record W3166943969 · doi:10.1002/cjce.24214

Microfluidic synthesis of platinum nanoparticles supported on reduced graphene oxide, titanium dioxide, and carbon for <scp>PEM</scp> fuel cells

2021· article· en· W3166943969 on OpenAlexvenueno aff
Prashant L. Suryawanshi, Sarang P. Gumfekar, Shirish H. Sonawane

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2021
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsnot available
Fundersnot available
KeywordsMaterials scienceCyclic voltammetryGrapheneChemical engineeringTitanium dioxideX-ray photoelectron spectroscopyPlatinum nanoparticlesLinear sweep voltammetryFourier transform infrared spectroscopyNanoparticleOxideElectrochemistryNanotechnologyElectrodeChemistryComposite material

Abstract

fetched live from OpenAlex

Abstract Platinum (Pt) nanoparticles on various supports, such as commercial carbon powder, titanium dioxide (TiO 2 ), and reduced graphene oxide (rGO), were synthesized using a continuous flow microfluidic system. First, the support materials were separately synthesized using the sonochemical technique followed by the loading of Pt. The Pt nanoparticles on different supports were characterized using Brunauer–Emmett–Teller (BET) for surface area and porosity analysis; X‐ray diffraction (XRD) for structural confirmation; Fourier transform infrared (FTIR) spectroscopy and X‐ray photoelectron spectroscopy (XPS) for surface composition; and transmission electron microscopy (TEM) for morphological investigation. Further, polymer electrolyte membrane (PEM) fuel cells were fabricated using the Pt nanoparticles on different supports, and cyclic voltammetry (CV), linear sweep voltammetry (LSV), and power density were performed. Among the three electrocatalysts, Pt/rGO showed the highest electrochemical performance. Pt/rGO showed higher specific activity (119 mA/cm 2 ), mass activity (238 mA/mg), current density (1274 mA/cm 2 ), and power density (497 mW/cm 2 ). We also determined the mass activity and specific activity of the electrocatalysts based on the electrochemical data. This work shows the potential of the microfluidic system to continuously synthesize the technologically important nanomaterials and their application for energy conversion devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.175
Teacher spread0.169 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2021
Admission routes1
Has abstractyes

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