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Record W3172800932 · doi:10.1515/hf-2021-0027

On-line characterization of wood chip brightness and chemical composition by means of visible and near-infrared spectroscopy

2021· article· en· W3172800932 on OpenAlexaff
Guillaume Hans, Bruce Allison

Bibliographic record

VenueHolzforschung · 2021
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsFPInnovations
Fundersnot available
KeywordsSoftwoodNear-infrared spectroscopyPulp (tooth)SpectrometerSpectroscopyMaterials scienceBrightnessChemometricsCalibrationChipLigninAnalytical Chemistry (journal)ChemistryOpticsComposite materialComputer scienceMathematicsEnvironmental chemistryChromatography

Abstract

fetched live from OpenAlex

Abstract Historically, on-line and real-time measurement of wood chip properties in the pulp and paper industry has been a challenge and has hampered the development of advanced process control strategies. In this study, visible and near-infrared (VIS-NIR) spectroscopy is investigated as a means to characterize wood chip brightness and chemical composition (i.e. extractives, lignin and holocellulose content) on-line. The estimated standard error on the holocellulose reference measurement was significantly reduced using data reconciliation. VIS-NIR calibration models were developed using partial least square regression. Derivative and baseline correction were found to be the most appropriate pre-processing methods. Model desensitization to the influence of moisture content and temperature by means of external parameter orthogonalization resulted in more robust models critical for on-line applications under harsh industrial conditions. Wavelength selection improved model accuracy for all properties. A comparison of two different spectrometer and probe combinations demonstrated that, after wavelengths selection, a non-contact measurement of wood chips performs as well as a contact measurement of wood powder for monitoring chemical composition. On-line prediction of wood chip brightness and chemical composition using the developed VIS-NIR models was demonstrated over 7 months in a kraft pulp mill processing both hardwood and softwood chips.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.593

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.253
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2021
Admission routes1
Has abstractyes

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