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NUDT15-mediated hydrolysis limits the efficacy of anti-HCMV drug ganciclovir

2021· article· en· W3175392988 on OpenAlexafffund
Si Min Zhang, Daniel Rehling, Ann‐Sofie Jemth, Adam Throup, Natalia Landázuri, Ingrid Almlöf, Mona Göttmann, Nicholas C.K. Valerie, Sanjay R. Borhade, Prasad B. Wakchaure, Brent D. G. Page, Matthieu Desroses, Evert Homan, Martin Scobie, Sean G. Rudd, Ulrika Warpman Berglund, Cecilia Söderberg‐Nauclér, Pål Stenmark, Thomas Helleday

Bibliographic record

VenueCell chemical biology · 2021
Typearticle
Languageen
FieldMedicine
TopicCytomegalovirus and herpesvirus research
Canadian institutionsUniversity of British Columbia
FundersBarncancerfondenAlfred Österlunds StiftelseScience for Life LaboratoryVetenskapsrådetKungliga Tekniska HögskolanKnut och Alice Wallenbergs StiftelseStiftelsen Felix Mindus Bidrag till LeukemiforskningenSvenska Sällskapet för Medicinsk ForskningCrafoordska StiftelsenH2020 European Research CouncilCancerfondenEuropean Research CouncilTorsten Söderbergs StiftelseMichael Smith Health Research BCPain Relief FoundationEuropean Federation of Pharmaceutical Industries and AssociationsMcGill UniversityKarolinska Institutet
KeywordsGanciclovirHuman cytomegalovirusNucleosideMetabolitePharmacologyChemistryActive metaboliteBiologyVirologyBiochemistryVirus

Abstract

fetched live from OpenAlex

Ganciclovir (GCV) is the first-line therapy against human cytomegalovirus (HCMV), a widespread infection that is particularly dangerous for immunodeficient individuals. Closely resembling deoxyguanosine triphosphate, the tri-phosphorylated metabolite of GCV (GCV-TP) is preferentially incorporated by the viral DNA polymerase, thereby terminating chain extension and, eventually, viral replication. However, the treatment outcome of GCV varies greatly among individuals, therefore warranting better understanding of its metabolism. Here we show that NUDT15, a Nudix hydrolase known to metabolize thiopurine triphosphates, can similarly hydrolyze GCV-TP through biochemical studies and co-crystallization of the NUDT15/GCV-TP complex. More critically, GCV efficacy was potentiated in HCMV-infected cells following NUDT15 depletion by RNAi or inhibition by an in-house-developed, nanomolar NUDT15 inhibitor, TH8321, suggesting that pharmacological targeting of NUDT15 is a possible avenue to improve existing anti-HCMV regimens. Collectively, the data further implicate NUDT15 as a broad-spectrum metabolic regulator of nucleoside analog therapeutics, such as thiopurines and GCV.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.046
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.294
Teacher spread0.273 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2021
Admission routes2
Has abstractyes

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