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Record W3178047631 · doi:10.1002/aenm.202100630

Porous Transport Layers for Proton Exchange Membrane Electrolysis Under Extreme Conditions of Current Density, Temperature, and Pressure

2021· article· en· W3178047631 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Energy Materials · 2021
Typearticle
Languageen
FieldEnergy
TopicHybrid Renewable Energy Systems
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceElectrolysisPorosityProton exchange membrane fuel cellBar (unit)Electrolysis of waterCurrent densityHydrogenWater transportChemical engineeringWater flowAnalytical Chemistry (journal)Composite materialEnvironmental engineeringFuel cellsChemistryEnvironmental scienceElectrodeEnvironmental chemistry

Abstract

fetched live from OpenAlex

Abstract Hydrogen produced via water electrolysis powered by renewable electricity or green H 2 offers new decarbonization pathways. Proton exchange membrane water electrolysis (PEMWE) is a promising technology although the current density, temperature, and H 2 pressure of the PEMWE will have to be increased substantially to curtail the cost of green H 2 . Here, a porous transport layer for PEMWE is reported, that enables operation at up to 6 A cm −2 , 90 ° C, and 90 bar H 2 output pressure. It consists of a Ti porous sintered layer (PSL) on a low‐cost Ti mesh (PSL/mesh‐PTL) by diffusion bonding. This novel approach does not require a flow field in the bipolar plate. When using the mesh‐PTL without PSL, the cell potential increases significantly due to mass transport losses reaching ca. 2.5 V at 2 A cm −2 and 90 ° C. On the other hand, the PEMWE with the PSL/mesh‐PTL has the same cell potential but at 6 A cm −2 , thus increasing substantially the operation range of the electrolyzer. Extensive physical characterization and pore network simulation demonstrate that the PSL/mesh‐PTL leads to efficient gas/water management in the PEMWE. Finally, the PSL/mesh‐PTL is validated in an industrial size PEMWE in a container operating at 90 bar H 2 output pressure.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.077
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.257
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it