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Record W3180510126 · doi:10.1029/2020gb006916

Continental and Ecoregion‐Specific Drivers of Atmospheric NO<sub>2</sub> and NH<sub>3</sub> Seasonality Over Africa Revealed by Satellite Observations

2021· article· en· W3180510126 on OpenAlexaff
Jonathan E. Hickman, Niels Andela, Kostas Tsigaridis, Corinne Galy‐Lacaux, Money Ossohou, Enrico Dammers, Martin Van Damme, Lieven Clarisse, Susanne E. Bauer

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2021
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsEnvironment and Climate Change Canada
FundersGoddard Space Flight CenterUniversities Space Research AssociationNational Aeronautics and Space Administration
KeywordsSeasonalityEnvironmental scienceEcoregionPrecipitationAtmospheric sciencesEcologyMeteorologyGeographyGeology

Abstract

fetched live from OpenAlex

Abstract Ammonia (NH 3 ) and nitrogen oxides (NO x : nitrogen dioxide [NO 2 ] + nitric oxide [NO]) play important roles in atmospheric chemistry. Throughout most of Africa, emissions of these gases are predominantly from soils and biomass burning. Here we use observations of tropospheric NO 2 vertical column densities (VCDs) from the Ozone Monitoring Instrument from 2005 through 2017 and atmospheric NH 3 VCDs from the Infrared Atmospheric Sounding Interferometer from 2008 through 2017 to evaluate seasonal variation of NO 2 and NH 3 VCDs across Africa and in seven African ecoregions. In regions where mean annual precipitation (MAP) is under 500 mm yr −1 , we find that NO 2 and NH 3 VCDs are positively related to monthly precipitation, and where MAP is between 500 and 1,750 mm yr −1 or higher, NO 2 VCDs are negatively related to monthly precipitation. In dry ecoregions, temperature and precipitation were important predictors of NH 3 and NO 2 VCDs, likely related to variation in soil emissions. In mesic ecoregions, monthly NO 2 VCDs were strongly related to burned area, suggesting that biomass burning drives seasonality. NH 3 VCDs in mesic ecoregions were positively related to both monthly temperature and monthly carbon monoxide (CO) VCDs, suggesting that a mixture of soil and biomass burning emissions influenced NH 3 seasonality. In northern mesic ecoregions, monthly temperature explained most of the variance in monthly NH 3 VCDs, suggesting that soil sources, including animal excreta, determined NH 3 seasonality. In southern mesic ecoregions, monthly CO VCDs explained more variation in NH 3 VCDs than temperature, suggesting that biomass burning may have greater influence over NH 3 seasonality.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.406
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.188
Teacher spread0.180 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations14
Published2021
Admission routes1
Has abstractyes

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