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Record W3180630501 · doi:10.1515/ipp-2020-4062

Effect of Uniaxial Stretching on Molecular Orientation, Crystallinity and Oxygen Permeability of Ethylene Vinyl Alcohol

2021· article· en· W3180630501 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueInternational Polymer Processing · 2021
Typearticle
Languageen
FieldMaterials Science
TopicSynthesis and properties of polymers
Canadian institutionsPolytechnique Montréal
Fundersnot available
KeywordsCrystallinityMaterials scienceOxygen permeabilityFourier transform infrared spectroscopyComposite materialVinyl alcoholUltimate tensile strengthPermeability (electromagnetism)OxygenChemical engineeringPolymerChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract This work studies the effects of uniaxial stretching on molecular orientation, crystallinity, crystallography and oxygen permeability of high barrier multilayer films based on EVOH barrier layer. Film samples were prepared using two different blow-up ratios (BUR) of 1 and 3. Uniaxial stretching was applied at 100°C using a tensile machine equipped with an environmental chamber. Fourier transform infrared (FTIR) spectroscopy was used to examine the molecular orientation in the EVOH layer before and after stretching and confirmed a considerable increase in the molecular orientation in the EVOH layer. Dynamic scanning calorimetry (DSC) and wide-angle X-ray diffraction (XRD) results point to the perfection of EVOH crystal structure by applying uniaxial stretching at high temperatures. Oxygen permeability results showed a considerable 25% decrease after stretching of the sample with lower BUR while a significant 80% reduction in oxygen permeability was observed for the sample prepared at higher BUR. The mechanism involved in increasing oxygen permeability due to the uniaxial stretching at high temperature is discussed in detail.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score0.414

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.287
Teacher spread0.276 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it