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Record W3181826649 · doi:10.1029/2020gc009582

Iron Mineralogy and Sediment Color in a 100 m Drill Core From Lake Towuti, Indonesia Reflect Catchment and Diagenetic Conditions

2021· article· en· W3181826649 on OpenAlexfundno aff
Rachel Y. Sheppard, R. E. Milliken, James M. Russell, E. C. Sklute, M. D. Dyar, Hendrik Vogel, Martin Melles, Satria Bijaksana, Ascelina Hasberg, Marina A. Morlock

Bibliographic record

VenueGeochemistry Geophysics Geosystems · 2021
Typearticle
Languageen
FieldComputer Science
TopicGeochemistry and Geologic Mapping
Canadian institutionsnot available
FundersSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen ForschungBrown UniversityGenome British ColumbiaDeutsche ForschungsgemeinschaftNASA Astrobiology InstituteNational Aeronautics and Space AdministrationNational Science Foundation
KeywordsDiagenesisGeologySedimentary rockSedimentary depositional environmentGeochemistryOverprintingSedimentMineralogyCarbonateMaficClay mineralsStructural basinGeomorphologyMetamorphic rockChemistry

Abstract

fetched live from OpenAlex

Abstract Iron is the most abundant redox‐sensitive element on the Earth's surface, and the oxidation state, mineral host, and crystallinity of Fe‐rich phases in sedimentary systems can record details of water‐rock interactions and environmental conditions. However, we lack a complete understanding of how these Fe‐rich materials are created, maintained, and oxidized or reduced in sedimentary environments, particularly those with mafic sources. The catchment of Lake Towuti, Indonesia, is known to contain a wide range of abundant crystalline Fe oxide, and the lake has a long sedimentary history. Here, we study a ∼100 m long drill core from the lake to understand patterns of sedimentation and how young iron‐rich sediments are affected by diagenesis through geologic time. We use visible/near infrared and Mössbauer spectroscopy, X‐ray diffraction, bulk chemistry measurements, and statistical cluster analysis to characterize the core sediment. We find that the core sediment can be divided into three statistically different zones dominated by Mg serpentine, Al clay minerals, and Fe 2+ carbonate, respectively. The entire core is rich in nanophase Fe, and elemental correlations and Fe mineralogy vary between these zones. The nanophase Fe is highly complex with both ferrous and ferric components, and contributes to, but does not dictate, variations in sediment color. We propose that the distinctive zones are the result of structural basin changes (notably river capture and shifting drainage patterns), and diagenetic overprinting caused by deep burial of reactive Fe. This complex record has implications for disentangling depositional and diagenetic trends in other mafic lacustrine systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.463
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.236
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2021
Admission routes1
Has abstractyes

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