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Record W3183210153 · doi:10.1149/ma2021-01192065mtgabs

Oil-Immersed Scanning Micropipette Contact Method Enabling Long-Term Corrosion Mapping

2021· article· en· W3183210153 on OpenAlexaff
Yuanjiao Li, Janine Mauzeroll

Bibliographic record

VenueECS Meeting Abstracts · 2021
Typearticle
Languageen
FieldEngineering
TopicAdhesion, Friction, and Surface Interactions
Canadian institutionsMcGill University
Fundersnot available
KeywordsCorrosionMicroscale chemistryMaterials scienceElectrolyteHumidityInertGalvanic cellContact angleEvaporationChemical engineeringMetallurgyComposite materialChemistryElectrode

Abstract

fetched live from OpenAlex

Scanning micropipette contact method (SMCM) suffers from droplet evaporation and crystallization which limits the use of most saline electrolyte solutions under natural air humidity. To overcome the limitations and expand the application of SMCM, we improve this technique by scanning the droplet under mineral oil that covers on the substrate surface. The hydrophobic and inert oil significantly enhances the droplet stability, allowing for prolonged mapping and the use of highly evaporative saline solutions regardless of ambient humidity levels. This systematic mapping technique was used to conduct a detailed investigation of localized corrosion taking place at the surface of an AA7075-T73 aluminum alloy in a 3.5 wt% NaCl electrolyte solution, which is typically challenging in the conventional SMCM. Maps of corrosion potentials and corrosion currents extracted from potentiodynamic polarization curves showed good correlations with the chemical composition of surface features and known galvanic interactions at the microscale level. This demonstrates the viability of the oil-immersed SMCM and opens up the avenue to mechanistic corrosion investigations at the microscale level using aqueous solutions that are prone to evaporation under noncontrolled humidity levels.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.087
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.263
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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