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Record W3191872092 · doi:10.1021/acsenergylett.1c01018

Toward Stable Monolithic Perovskite/Silicon Tandem Photovoltaics: A Six-Month Outdoor Performance Study in a Hot and Humid Climate

2021· article· en· W3191872092 on OpenAlexaff
Michele De Bastiani, Emmanuel Van Kerschaver, Quentin Jeangros, Atteq ur Rehman, Erkan Aydın, Furkan H. Isikgor, Alessandro J. Mirabelli, Maxime Babics, Jiang Liu, Shynggys Zhumagali, Esma Ugur, George T. Harrison, Thomas G. Allen, Bin Chen, Yi Hou, Semen Shikin, Edward H. Sargent, Christophe Ballif, Michaël Salvador, Stefaan De Wolf

Bibliographic record

VenueACS Energy Letters · 2021
Typearticle
Languageen
FieldEngineering
TopicPerovskite Materials and Applications
Canadian institutionsUniversity of Toronto
FundersOffice of Naval Research GlobalBundesamt für EnergieKing Abdullah University of Science and TechnologySchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
KeywordsPerovskite (structure)PhotovoltaicsTandemSiliconMaterials scienceDegradation (telecommunications)Open-circuit voltagePhotovoltaic systemNanotechnologyEngineering physicsOptoelectronicsVoltageChemical engineeringElectrical engineeringComposite materialEngineering

Abstract

fetched live from OpenAlex

Perovskite/silicon tandem solar cells are emerging as a high-efficiency and prospectively cost-effective solar technology with great promise for deployment at the utility scale. However, despite the remarkable performance progress reported lately, assuring sufficient device stability—particularly of the perovskite top cell—remains a challenge on the path to practical impact. In this work, we analyze the outdoor performance of encapsulated bifacial perovskite/silicon tandems, by carrying out field-testing in Saudi Arabia. Over a six month experiment, we find that the open circuit voltage retains its initial value, whereas the fill factor degrades, which is found to have two causes. A first degradation mechanism is linked with ion migration in the perovskite and is largely reversible overnight, though it does induce hysteretic behavior over time. A second, irreversible, mechanism is caused by corrosion of the silver metal top contact with the formation of silver iodide. These findings provide directions for the design of new and more stable perovskite/silicon tandems

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.208
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations84
Published2021
Admission routes1
Has abstractyes

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Same venueACS Energy LettersSame topicPerovskite Materials and ApplicationsFrench-language works237,207