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Record W3191989513 · doi:10.1002/cjce.24278

Layer‐by‐layer self‐assembly of polyethersulphone microfiltration membranes for dye removal and flux recovery improvement

2021· article· en· W3191989513 on OpenAlexvenueno aff
Luiz Henrique Biscaia Ribeiro da Silva, Rebecca Manesco Paixão, Rosângela Bergamasco, Angélica Marquetotti Salcedo Vieira, Marcelo Fernandes Vieira

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2021
Typearticle
Languageen
FieldEnvironmental Science
TopicMembrane Separation Technologies
Canadian institutionsnot available
Fundersnot available
KeywordsMembraneMicrofiltrationFourier transform infrared spectroscopyChemical engineeringAttenuated total reflectionFiltration (mathematics)Contact angleChemistryScanning electron microscopeLayer (electronics)ChromatographyMaterials scienceComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Commercial polyethersulphone (PES) microfiltration (MF) membranes were modified with sulphuric acid, chitosan (CHS), and graphene oxide (GO) by the layer‐by‐layer self‐assembly method via electrostatic interaction using a pressurized filtration system. The sulphonation of the PES MF membranes was achieved through the filtration of a 10 wt.% sulphuric acid solution. The negatively charged surface of the PES MF membrane allowed the interaction between amino groups present in CHS, and finally, the membrane substrate received a negatively charged layer through the filtration of a GO solution. Characterization analysis such as contact angle, scanning electron microscopy (SEM), and attenuated total reflectance‐Fourier transform infrared spectroscopy (ATR‐FTIR) proved that the membranes were successfully modified. The effect of CHS and GO masses were analyzed, the membrane that showed the best performance was MF CHS 1 GO 0.5 with a rejection of 100% of the Reactive Black 5 (RB5) dye, hydraulic permeability of 10.18 L/m 2 · h · bar, and flux recovery ratio of 71.21%. Also, this membrane was able to be reused in three cycles, maintaining a rejection of RB5 higher than 85% during the last cycle. Therefore, the study provides an interesting alternative for the removal of anionic dyes solubilized in water from the textile industry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.310

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.199
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2021
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical EngineeringSame topicMembrane Separation TechnologiesFrench-language works237,207