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Record W3193042220 · doi:10.14351/0831-4985-34.1.11

Salting Out: A Simple and Reliable Method to Distinguish Between Common Fluid Preservatives and Estimate Alcohol Concentration

2020· article· en· W3193042220 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCollection Forum · 2020
Typearticle
Languageen
FieldArts and Humanities
TopicConservation Techniques and Studies
Canadian institutionsnot available
Fundersnot available
KeywordsPreservativeSaltingSalting outChemistryChromatographyPulp and paper industryOrganic chemistryEngineeringFood science

Abstract

fetched live from OpenAlex

Abstract This paper details the salting-out method, which uses the salts potassium carbonate and sodium chloride to distinguish between the three most commonly used fluid preservatives: ethanol, isopropanol, and formalin. A summary of other methods to identify fluid preservative type and a review of the salting-out method published by Mayfield (2013, Distinguishing between ethanol and isopropanol in natural history collection fluid storage, Society for the Preservation of Natural History Collections , https://spnhc.org/wp-content/uploads/2018/11/Mayfieldfinalwithtablechanges.pdf ) are provided. A new salting-out method is presented, which requires a small fluid sample (2–4 ml). It is simple, quick, and relatively inexpensive to implement, making it a viable method to distinguish between common fluid preservatives. The materials and equipment for the salting-out test cost just over $100 US, and tests take approximately 3 minutes per container. Results of testing on known concentrations and combinations of ethanol, isopropanol, and formalin (a solution of formaldehyde in water) and on samples of fluid preservatives from specimen containers in the Smithsonian National Museum of Natural History and Bernice Pauahi Bishop Museum collections are presented. The results of salting-out tests have been verified by direct analysis in real time mass spectrometry (DART-MS) (Cody et al., 2005, Versatile new ion source for the analysis of materials in open air under ambient conditions, Analytical Chemistry 77(8):2297–302), which confirmed the results of salting-out tests but also highlighted some limitations, particularly when combinations of fluid preservative are encountered.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.522
Threshold uncertainty score0.677

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.093
GPT teacher head0.339
Teacher spread0.246 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it