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Record W3194576772 · doi:10.5382/econgeo.4843

In Situ Multiple Sulfur Isotope and S/Se Composition of Magmatic Sulfide Occurrences in the Labrador Trough, Northern Quebec

2021· article· en· W3194576772 on OpenAlexaffabout
William D. Smith, Wolfgang D. Maier, I. Bliss, Laure Martin

Bibliographic record

VenueEconomic Geology · 2021
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsNatural Resources Canada
Fundersnot available
Keywordsδ34SGeochemistryGeologySulfideSulfurMaficMantle (geology)Hydrothermal circulationChemistryFluid inclusionsPaleontology

Abstract

fetched live from OpenAlex

Abstract The interaction between mafic-ultramafic magma and crustal sulfide is considered a key process in the formation of magmatic Ni-Cu-platinum group element (PGE) sulfide deposits. Integrated S/Se and multiple sulfur isotope studies are the most robust in constraining the role of crustal sulfur during ore genesis. In the present study, we report the first integrated S/Se and multiple sulfur isotope study of magmatic sulfide occurrences in the Labrador Trough, namely, on the recently discovered Idefix PGE-Cu and Huckleberry Cu-Ni-(PGE) prospects. Whole-rock and in situ S/Se values (~810–3115) of magmatic sulfides and their host rocks are consistent with S loss during postmagmatic hydrothermal alteration, negating their use in interpreting the origin of S. Values of ∆33S ~0 indicate no record of the assimilation of Archaean sulfur. Disseminated (–0.5 to +2.5‰) and globular (3.0–4.5‰) sulfides at Idefix as well as globular sulfides (2.1–9.6‰) at Huckleberry have δ34S values greater than the accepted mantle range, suggesting that crustal S played a role in the formation of these sulfides. In contrast, disseminated and net-textured sulfides at Huckleberry have variable δ34S values (–4.6 to +3.2‰) that are mostly within the accepted mantle range, excluding one anomalous sample that records relatively higher δ34S values (11.9–15.0‰). It is proposed that sulfide melt segregated in response to the addition of small proportions of crustal S prior to the final emplacement of the host intrusions, i.e., in a feeder conduit or staging chamber. Isotopic exchange between the sulfide melt and silicate magma has diluted and, in places, eradicated a crustal δ34S signature.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.797
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.202
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2021
Admission routes2
Has abstractyes

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