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Record W3199214419 · doi:10.1002/rcm.9204

An arithmetic correction for the effect of lipid on carbon stable isotope ratios in muscle and digestive glands of the American lobster ( <scp> <i>Homarus americanus</i> </scp> )

2021· article· en· W3199214419 on OpenAlexafffund
Jonathan Fischer‐Rush, Rémy Rochette, Emily Paton, Alexandrea Dickey, Brian Hayden

Bibliographic record

VenueRapid Communications in Mass Spectrometry · 2021
Typearticle
Languageen
FieldEnvironmental Science
TopicIsotope Analysis in Ecology
Canadian institutionsSaint John Regional HospitalUniversity of New Brunswick
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of New Brunswick
KeywordsHomarusAkaike information criterionChemistryRange (aeronautics)Extraction (chemistry)American lobsterStable isotope ratioZoologyStatisticsChromatographyBiologyCrustaceanMathematicsPhysics

Abstract

fetched live from OpenAlex

Rationale Lipid correction models use elemental carbon‐to‐nitrogen ratios to estimate the effect of lipids on δ 13 C values and provide a fast and inexpensive alternative to chemically removing lipids. However, the performance of these models varies, especially in whole‐body invertebrate samples. The generation of tissue‐specific lipid correction models for American lobsters, both an ecologically and an economically important species in eastern North America, will aid ecological research of this species and our understanding of the function of these models in invertebrates. Method We determined the δ 13 C and δ 15 N values before and after lipid extraction in muscle and digestive glands of juvenile and adult lobster. We assessed the performance of four commonly used models (nonlinear, linear, natural logarithm (LN) and generalized linear model (GLM)) at estimating lipid‐free δ 13 C values based on the non‐lipid‐extracted δ 13 C values and elemental C:N ratios. The accuracy of model predictions was tested using paired t ‐tests, and the performance of the different models was compared using the Akaike information criterion score. Results Lipid correction models accurately estimated post‐lipid‐extraction δ 13 C values in both tissues. The nonlinear model was the least accurate for both tissues. In muscle, the three other models performed well, and in digestive glands, the LN model provided the most accurate estimates throughout the range of C:N values. In both tissues, the GLM estimates were not independent of the post‐lipid‐extraction δ 13 C values, thus reducing their transferability to other datasets. Conclusions Whereas previous work found that whole‐body models poorly estimated the effect of lipids in invertebrates, we show that tissue‐specific lipid correction models can generate accurate and precise estimates of lipid‐free δ 13 C values in lobster. We suggest that the tissue‐specific logarithmic models presented here are the preferred models for accounting for the effect of lipid on lobster isotope ratios.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.009
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.012
Threshold uncertainty score0.025

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0030.009
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.247
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2021
Admission routes2
Has abstractyes

Explore more

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