Building a Shp: A New Rare-Earth Metal-Organic Framework and Its Application in a Catalytic Photo-Oxidation Reaction
Bibliographic record
Abstract
The design and synthesis of new metal–organic frameworks (MOFs) is important from both a fundamental and application standpoint. In this work, a novel, highly‐connected rare‐earth (RE) MOF with shp topology is reported, named RE‐CU‐10 (RE = rare‐earth, CU = Concordia University), comprised of nonanuclear RE(III)‐cluster nodes and tetratopic pyrene‐based linkers. This represents the first time that the 1,3,6,8‐tetrakis(p‐benzoic acid)pyrene (H4TBAPy) linker is integrated in the shp topology. Y‐CU‐10 was explored as a heterogeneous photocatalyst for the selective oxidation and detoxification of a sulfur mustard simulant, 2‐chloroethyl ethyl sulfide (2‐CEES), showing a halflife for conversion to the less toxic 2‐chloroethyl ethyl sulfoxide (2‐CEESO) of 6.0 min.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".