Efficient one-pot synthesis of 4-hydroxy-2<i>H</i> chromene by heterogeneously catalyzed ZnO NP and mesoporous aluminosilicate catalysts in solvent free condition
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Bibliographic record
Abstract
4-Hydroxy-2H chromenes are fused benzopyran rings, an important class of biologically active compounds that are widely used as antibacterial, antiviral, antitumor, and anticancer agents. In this paper, we report the synthesis of 4-hydroxy-2H chromenes using two catalysts: (i) ZnO nanoparticles and (ii) mesoporous ZnO/AlSBA-15(7). The ZnO nanoparticle catalyst was prepared using leaf extract, and ZnO/AlSBA-15(7) catalysts were prepared by a wet chemical route. All catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy, and N 2 sorption techniques. The catalytic activity of the synthesized catalyst was evaluated in a one-pot reaction using aromatic aldehyde and coumarin and was found to have a maximum yield of 81% at 80 °C, with a catalyst dose of 10 mmol %, and in a time limit of 4 h.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it