Hybrid Inorganic-Organic Perovskite Glasses
Bibliographic record
Abstract
Hybrid perovskites occupy a prominent position within solid-state materials chemistry due to their (e.g.) ionic transport, ferroelectric and multiferroic properties. Here we show that a series of [TPrA][M(Dca) 3 ] perovskites (TPrA = tetrapropylammonium cation; Dca = dicyanamide anion; M = Mn, Fe, Co) melt below 300 °C. A combined experimental-computational approach reveal the melting mechanism, and demonstrates that the hybrid perovskites form glasses upon melt quenching which largely retain the inorganic-organic bonding of the crystalline phase. The very low thermal conductivities of these glasses (~ 0.2 W m -1 K -1 ), moderate electrical conductivities (10 -2 – 10 -4 S m -1 ) and thermo-mechanical properties reminiscent of polymeric materials identify them as a new family of functional glass-formers.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".