Crystal and molecular structures of some phosphane-substituted cymantrenes [(C<sub>5</sub>H<sub>4</sub> <i>X</i>)Mn(CO)<i>LL</i>′] (<i>X</i> = H or Cl, <i>L</i> = CO, <i>L</i>′ = PPh<sub>3</sub> or PCy<sub>3</sub>, and <i>LL</i>' = Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)
Bibliographic record
Abstract
UV irradiation of tetrahydrofuran solutions of [CpMn(CO) 3 ] (Cp = π-C 5 H 5 or π-C 5 H 4 Cl) in the presence of the phosphanes PPh 3 or PCy 3 (Cy = cyclohexyl) and Ph 2 PCH 2 CH 2 PPh 2 yields the substitution products [CpMn(CO) 2 P R 3 ] ( R = Ph or Cy) and [CpMn(CO)(Ph 2 PCH 2 CH 2 PPh 2 )], namely, dicarbonyl(η 5 -cyclopentadienyl)(triphenylphosphane-κ P )manganese(I), [Mn(C 5 H 5 )(C 18 H 15 P)(CO) 2 ], 1a , dicarbonyl(η 5 -1-chlorocyclopentadienyl)(triphenylphosphane-κ P )manganese(I), [Mn(C 5 H 4 Cl)(C 18 H 15 P)(CO) 2 ], 1b , dicarbonyl(η 5 -cyclopentadienyl)(tricyclohexylphosphane-κ P )manganese(I), [Mn(C 5 H 5 )(C 18 H 33 P)(CO) 2 ], 2a , dicarbonyl(η 5 -1-chlorocyclopentadienyl)(tricyclohexylphosphane-κ P )manganese(I), [Mn(C 5 H 4 Cl)(C 18 H 33 P)(CO) 2 ], 2b , carbonyl(η 5 -cyclopentadienyl)[1,2-bis(diphenylphosphanyl)ethane-κ 2 P , P ′]manganese(I), [Mn(C 5 H 5 )(C 26 H 24 P 2 )(CO)], 3a , and carbonyl(η 5 -1-chlorocyclopentadienyl)[1,2-bis(diphenylphosphanyl)ethane-κ 2 P , P ′]manganese(I), [Mn(C 5 H 4 Cl)(C 26 H 24 P 2 )(CO)], 3b , The crystal structure determinations show a very small influence of the chlorine substitution and a moderate influence of the phosphane substitution on the bond lengths. The P R 3 groups avoid being eclipsed with the C—Cl bonds. All the compounds employ weak C—H...O interactions for intermolecular association, which are enhanced by C—H...Cl contacts in the chlorinated products.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.002 |
| Meta-epidemiology (narrow) | 0.009 | 0.010 |
| Meta-epidemiology (broad) | 0.009 | 0.005 |
| Bibliometrics | 0.002 | 0.009 |
| Science and technology studies | 0.005 | 0.006 |
| Scholarly communication | 0.003 | 0.004 |
| Open science | 0.005 | 0.004 |
| Research integrity | 0.006 | 0.008 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".