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Record W3204253514 · doi:10.1016/j.egyr.2021.09.068

Enhancement of fuel and physicochemical properties of canola residues via microwave torrefaction

2021· article· en· W3204253514 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnergy Reports · 2021
Typearticle
Languageen
FieldEngineering
TopicThermochemical Biomass Conversion Processes
Canadian institutionsMemorial University of NewfoundlandUniversity of Saskatchewan
Fundersnot available
KeywordsTorrefactionHeat of combustionCoalFourier transform infrared spectroscopyBiofuelPulp and paper industryBiomass (ecology)ChemistryMaterials scienceCanolaChemical engineeringWaste managementOrganic chemistryPyrolysisAgronomyCombustionFood science

Abstract

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Conversion of low value agricultural residues to better-quality products e.g. biofuel, bioproducts can solve the issues related to energy crisis as well as environmental challenges. Torrefaction, a thermochemical pretreatment was employed on canola residue (CR) to augment the physicochemical properties of biomass for heat and energy applications. In the present study, the effects of microwave torrefaction on canola residue have been investigated for the following operating parameters: microwave power (250–450 W), residence time (10–20 min), and feeding load (70–110 g). Box Behnken design method was used to design the experiments and find the interaction between process parameters. Both mass and energy yields diminished with rise in microwave power and torrefaction reaction time. The results show that the carbon content significantly increased with degree of torrefaction while oxygen content had a reverse trend, therefore the atomic ratio of torrefied biomass reduced remarkably. Torrefied biomass shows higher carbon percentages than that for the bituminous coal. In addition, a noticeable decrease in volatile matter was observed with growth in torrefaction severity and thus increased fixed carbon content. The higher heating value (HHV) was boosted up by 26% (promoted from 17.8 MJ/kg to 22.4 MJ/kg). HHV of highly torrefied canola residue is very close to bituminous coal. Fourier transform infrared spectroscopy (FTIR) analysis showed that surface functional groups for example OH, CH, and CO decreased with torrefaction severity indicating the improvement of hydrophobicity of torrefied biomass. Scanning electron microscopy (SEM) results represent a more porous structure at highest torrefaction conditions which happened due to thermal cracking and decomposition of lignin and decreased the grinding energy by 89% compared to that for raw biomass. Moreover, inductively coupled plasma-mass spectrometry (ICP) analysis data showed that concentrations of minerals, alkaline and other essential element amplified with degree of torrefaction. The influence of microwave power was the highest on properties of torrefied biomass, followed by residence time and feeding load. The optimum torrefaction conditions were found at 450W with 90 g feeding load for residence time of 20 min.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.318

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.182
Teacher spread0.175 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it