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Record W3209209586 · doi:10.1002/anie.202111796

Cover Picture: Radical‐Bridged Ln<sub>4</sub> Metallocene Complexes with Strong Magnetic Coupling and a Large Coercive Field (Angew. Chem. Int. Ed. 45/2021)

2021· paratext· en· W3209209586 on OpenAlexaff
Niki Mavragani, Dylan Errulat, Diogo A. Gálico, Alexandros A. Kitos, Akseli Mansikkamäki, Muralee Murugesu

Bibliographic record

VenueAngewandte Chemie International Edition · 2021
Typeparatext
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsDelocalized electronCoercivityRadicalCover (algebra)MetalloceneField (mathematics)Magnetic fieldCoupling (piping)Materials scienceMagnetCondensed matter physicsChemistryComputational chemistryCrystallographyPhysicsOrganic chemistryPolymerPolymerizationMetallurgyEngineeringMechanical engineeringQuantum mechanics

Abstract

fetched live from OpenAlex

Enhancing magnetic coupling in 4f-based single-molecule magnets is an ongoing challenge. In their Research Article on page 24206, Akseli Mansikkamäki, Muralee Murugesu and co-workers have incorporated highly delocalized tetrazinyl radicals to bridge 4f metallocenes, forming tetranuclear complexes. A thorough examination of the magnetic properties and computational studies support a radical-induced “giant-spin” model with strong exchange interactions, zero-field SMM behaviour and a giant coercive field of 3 T.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.488
Threshold uncertainty score0.731

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0020.002
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.4880.160

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.251
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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Same venueAngewandte Chemie International EditionSame topicMagnetism in coordination complexesFrench-language works237,207