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Record W3215840534 · doi:10.1063/pt.3.4893

More on Arrhenius plots

2021· article· en· W3215840534 on OpenAlexaff
R. A. Masut

Bibliographic record

VenuePhysics Today · 2021
Typearticle
Languageen
FieldMaterials Science
TopicElectron and X-Ray Spectroscopy Techniques
Canadian institutionsPolytechnique Montréal
Fundersnot available
KeywordsFermi–Dirac statisticsPhysicsBoltzmann constantElectronBoltzmann distributionFermi energyArrhenius equationInverseCondensed matter physicsBoltzmann equationQuantum mechanicsStatistical physicsMathematics

Abstract

fetched live from OpenAlex

Axel Lorke’s Quick Study (Physics Today, May 2021, page 66) discusses underlying connections between seemingly unrelated phenomena. His brief reminder of Svante Arrhenius’s major contributions to science—and in particular, his now-famous empirical relation describing the rate of thermally activated processes—is thought-provoking.There is, however, a minor point appearing in the caption of figure 2, showing electron density versus inverse temperature, that needs clarification. If we concentrate on the high-temperature (left) portion of the graph, the “reaction” involved is the generation of an electron–hole pair (analogous to electron–positron pair production in particle physics), for which the Gibbs free-energy change is what is known as the energy gap Eg. For that reaction, the product of the electron density n and hole density p is given by np∝exp(−Eg/kBT), where kB is the Boltzmann constant and T is absolute temperature.11. C. D. Thurmond, J. Electrochem. Soc. 122, 1133 (1975). https://doi.org/10.1149/1.2134410 At the high temperatures on the left side of the graph, the semiconductor is nearly intrinsic, so n≈p∝exp(−Eg/2kBT), which is where the factor of two in the denominator of the slope originates.The caption states that the “factor of two in the denominator arises because electrons obey Fermi–Dirac statistics rather than classical Boltzmann distribution.” But at such high temperatures, Fermi–Dirac statistics approximates the Boltzmann distribution, so it cannot be the reason for the factor of two as the caption states. A similar explanation applies to the ionization of neutral donors.22. R. W. Christy, Am. J. Phys. 40, 40 (1972). https://doi.org/10.1119/1.1986444ReferencesSection:ChooseTop of pageReferences <<1. C. D. Thurmond, J. Electrochem. Soc. 122, 1133 (1975). https://doi.org/10.1149/1.2134410, Google ScholarCrossref2. R. W. Christy, Am. J. Phys. 40, 40 (1972). https://doi.org/10.1119/1.1986444, Google ScholarCrossref, ISI© 2021 American Institute of Physics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.036
Threshold uncertainty score0.579

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.288
Teacher spread0.273 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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