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Record W3216084404 · doi:10.1002/celc.202100958

A Flexible Ionic Polymer for “Soft Machines” – Where is the Low Temperature Limit?

2021· article· en· W3216084404 on OpenAlexafffund
Jake Thibodeau, Anna Ignaszak

Bibliographic record

VenueChemElectroChem · 2021
Typearticle
Languageen
FieldEngineering
TopicAdvanced Sensor and Energy Harvesting Materials
Canadian institutionsUniversity of New Brunswick
FundersDalhousie University
KeywordsSelf-healing hydrogelsIonic conductivityMaterials scienceGlycerolSoft roboticsConductivityIonic bondingPolymerChemical engineeringNanotechnologyComposite materialPolymer chemistryElectrical engineeringChemistryIonElectrolyteOrganic chemistryEngineeringActuator

Abstract

fetched live from OpenAlex

Abstract Soft wearable robotics, electronic skins, exoskeletons, implantable drug delivery, medical sensors, fitness trackers as well as flexible power sources (batteries, capacitors, fuel cells) are emerging technologies that require significant innovation to succeed. Conducting hydrogels are one of the promising flexible platforms that can adopt a modular specification of wearable electronics. However, a common difficulty arises from incorporation of water that serves as main facilitator of ionic conductivity for these materials. This results in severe loss of performance when need to operate below freezing point of water. This work shows that the hydrogel with 50 vol % of glycerol with respect to water content can nominally support a modest weight at room temperature (360 g), and a significantly higher weight (1.5 kg) when cooled to −60 °C. Unlike other formulations, this hydrogel remained transparent at extremely low temperatures and thus could be useful in flexible optical devices. At −20 °C, conductivity of hydrogel without anti‐freeze drops below 2×10 −4 S cm −1 , with 25–50 vol % of glycerol ranging at ∼0.5 to 4×10 −3 S cm −1 . Furthermore, at −40 °C the hydrogel without glycerol becomes an insulator (∼2×10 −6 S cm −1 ), and the one with 50 vol % glycerol shows ionic conductivity in the range of 1–4 ×10 −4 S cm −1 . Altogether, we define the operational temperature limit at −40 °C with respect to the ionic conductivity and at −60 °C in terms of sufficient mechanical strength for the hydrogel containing 50 vol % glycerol.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.022
Threshold uncertainty score0.698

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.218
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2021
Admission routes2
Has abstractyes

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