Synthèses et Caractérisations de Dispersions de Polymères dans un Solvant Organique Polymérisable
Bibliographic record
Abstract
L’objectif consistait a preparer une dispersion de polymere P1, en partant d’un monomere M1, dans un solvant M2 polymerisable, tel un monomere ou un oligomere telechelique. Ceci necessite que M1 et M2, miscibles ou non miscibles au depart, soient polymerisables par des methodes differentes. Le systeme M1 / M2 vinylpyrrolidone (VP) / poly(dimethylsiloxane) diglycidyl ether (PDMS DGE) forme une emulsion huile-huile au depart qui par polymerisation radicalaire de la VP conduit a une dispersion de poly(VP) dans une phase continue PDMS DGE, dont la reticulation a pu etre effectuee par une polyamine. Le systeme acetate de vinyle (AcV) / PDMS DGE, homogene au depart, conduit par une polymerisation radicalaire precipitante a une dispersion de poly(AcV) dans une phase PDMS DGE. Le 3eme est celui d’une polycondensation de polyol-diisocyanate en milieu PDMS DGE. Des etudes cinetiques et granulometriques ont ete effectuees pour ces 3 systemes.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.001 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".