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Record W4200031641 · doi:10.1002/essoar.10509739.1

Uncertainty in fire emission factors and the impact on modeled atmospheric CO and O3

2021· preprint· en· W4200031641 on OpenAlexfundno aff
Rebecca R. Buchholz, Wenfu Tang, L. K. Emmons, Benjamin Gaubert, Forrest Lacey, Mijeong Park, Simone Tilmes, Rebecca H. Schwantes, Christine Wiedinmyer, H. M. Worden

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsnot available
FundersNational Aeronautics and Space AdministrationCanadian Space AgencyNational Science Foundation
KeywordsEnvironmental scienceAtmospheric sciencesAtmospheric chemistryTroposphereCombustionOzoneAtmospheric compositionVegetation (pathology)Emission inventoryCarbon monoxideAir pollutionMeteorologyAtmosphere (unit)Environmental chemistryChemistryAir quality indexGeographyPhysics

Abstract

fetched live from OpenAlex

Fire emissions are an important component of global models, which help to understand the influence of sources, transport and chemistry on atmospheric composition. Global fire emission inventories can vary substantially due to the assumptions made in the emission creation process, including the defined vegetation type, fire detection, fuel loading, fraction of vegetation burned and emissions factors. Here, we focus on the uncertainty in emission factors and the resulting impact on modeled composition. Our study uses the Community Atmosphere Model with chemistry (CAM-chem) to model atmospheric composition for 2014, a year chosen for the relatively quiet El Niño Southern Oscillation activity. We focus on carbon monoxide (CO), a trace gas emitted from incomplete combustion and also produced from secondary oxidation of volatile organic compounds (VOCs). Fire is a major source of atmospheric CO and VOCs. Modeled CO from four fire emission inventories (CMIP6/GFED4s, QFED2.5, GFAS1.2 and FINN1.5) are compared after being implemented in CAM-chem. Multiple sensitivity tests are performed based on CO and VOC emission factor uncertainties. We compare model output in the 14 basis regions defined by the Global Fire Emissions Database (GFED) team and evaluate against CO observations from the Measurements of Pollution in the Troposphere (MOPITT) satellite-based instrument. For some regions, emission factor uncertainty spans the results found by using different inventories. Finally, we use modeled ozone (O3) to briefly investigate how emission factor uncertainty influences the atmospheric oxidative environment. Overall, accounting for emission factor uncertainty when modeling atmospheric chemistry can lend a range of uncertainty to simulated results.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.005
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.064
Threshold uncertainty score0.127

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.005
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.002
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.231
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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